منابع مشابه
Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
Multinuclear solid-state nuclear magnetic resonance, mass spectrometry, first-principles molecular dynamics simulations, and other complementary evidence reveal that the coordination environment around the Zn(2+) ions in MOF-5, one of the most iconic materials among metal-organic frameworks (MOFs), is not rigid. The Zn(2+) ions bind solvent molecules, thereby increasing their coordination numbe...
متن کاملSonochemical synthesis of MOF-5.
High quality MOF-5 crystals of 5-25 mum in size were prepared for the first time using a sonochemical method in substantially reduced synthesis time (ca. 30 min) compared with conventional solvothermal synthesis (24 h).
متن کاملMOF-5 composites exhibiting improved thermal conductivity
The low thermal conductivity of the prototype hydrogen storage adsorbent, metal-organic framework 5 (MOF-5), can limit performance in applications requiring rapid gas uptake and release, such as in hydrogen storage for fuel cell vehicles. As a means to improve thermal conductivity, we have synthesized MOF-5-based composites containing 1e10 wt.% of expanded natural graphite (ENG) and evaluated t...
متن کاملWater Adsorption and Insertion in MOF‐5
The high surface areas and tunable properties of metal−organic frameworks (MOFs) make them attractive materials for applications in catalysis and the capture, storage, and separation of gases. Nevertheless, the limited stability of some MOFs under humid conditions remains a point of concern. Understanding the atomic-scale mechanisms associated with MOF hydrolysis will aid in the design of new c...
متن کاملOvertone Spectroscopy of Hydrogen in MOF-5
Acknowledgements First and foremost I would like to thank my adviser Professor Stephen FitzGerald for his advice and support, for always making time to answer my questions and for showing me how fascinating, frustrating and rewarding experimental physics can be. I am grateful for the opportunity to pursue this work which has been a significant and enjoyable part of my time at Oberlin. I thank m...
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ژورنال
عنوان ژورنال: RSC Advances
سال: 2020
ISSN: 2046-2069
DOI: 10.1039/d0ra02509g